GALLERY: Click the image above to view more photos of Daphne Guiness and her coutoure collection.

Daphne Guinness collects 10-inch platform heels and couture garments the way some extreme connoisseurs collect artwork or memorabilia. She amasses them in nearly unbelievable quantities.

In a detailed interview with The New Yorker for a profile published this week, the brewery heiress told the magazine she had 2,500 pieces in her wardrobe, along with 450 pairs of shoes — nearly all by the most sought after and highly recognized creators in the business.

Approximately 100 of those garments and accessories are on display at The Museum at the Fashion Institute of Technology, including haute couture from Chanel, Dior, Givenchy, Lacroix and Valentino. The ”Daphne Guinness” exhibition is one of only a handful the space has dedicated to what FIT calls “individual women of style,” or “style icons.”

Daphne Guinness (shoe detail) at the Steven Klein's "Time Capsule" Video Installation Preview at the Park Avenue Armory on Sept. 12, 2011 in New York City. (Mark Von Holden/GETTY IMAGES)

Guinness, who consistently demonstrates her intrepid approach to fashion, has become a creator and style governess in her own right, stimulating the designers with whom she has grown close. One such designer and friend was the late Alexander McQueen. Two dozen of his garments that have never previously been displayed are featured in the exhibit.

In addition to her wild bleach-and-black striped mane, Guinness has become known for her unpredictable public comments. In Rebecca Mead’s article for The New Yorker, Guinness was quoted telling her assistant “I’ll eat when I’m dead,” when urged to eat some pasta, which has stirred up the blogosphere.

Part of the Daphne Guinness Exhibit at the Fashion Institute of Technology. (Eileen Costa/Fashion Institute of Technology)