"Gossip Girl” (Giovanni Rufino/THE CW)

It’s the first time CW has made its shows available through a provider’s Video On Demand service. And now, shows like “Gossip Girl” and “Vampire Diaries” will be availble for Comcast customers the day after they air, and also include the four most-recent episodes.

In addition, other shows that will be available include “America’s Next Top Model,” “Supernatural,” “Hart of Dixie,” “90210,” “Nikita,’ “Beauty and the Beast,’ “Emily Owens, MD” and “Arrow,” which recently scored big ratings for the network.